| Total | Matches | Wins | Draws | Losses | |||
|---|---|---|---|---|---|---|---|
| Total | 40 | 11 | (28%) | 15 | (38%) | 14 | (35%) |
| Home | 20 | 6 | (30%) | 9 | (45%) | 5 | (25%) |
| Away | 20 | 5 | (25%) | 6 | (30%) | 9 | (45%) |
L | 2022-05-03 | Villarreal |  | 2-3 |  | Liverpool | SF | ||
L | 2022-04-27 | Liverpool | | 2-0 | | Villarreal | SF | ||
D | 2022-04-12 | Bayern München |  | 1-1 | | Villarreal | QF | ||
W | 2022-04-06 | Villarreal | | 1-0 | | Bayern München | QF | ||
W | 2022-03-16 | Juventus |  | 0-3 | | Villarreal | L16 | ||
D | 2022-02-22 | Villarreal | | 1-1 | | Juventus | L16 | ||
W | 2021-12-09 | Atalanta |  | 2-3 | | Villarreal | D6 | ||
L | 2021-11-23 | Villarreal | | 0-2 |  | Manchester United | D5 | ||
W | 2021-11-02 | Villarreal | | 2-0 |  | Young Boys | D4 | ||
W | 2021-10-20 | Young Boys | | 1-4 | | Villarreal | D3 | ||
L | 2021-09-29 | Manchester United | | 2-1 | | Villarreal | D2 | ||
D | 2021-09-14 | Villarreal | | 2-2 | | Atalanta | D1 | ||
L | 2011-12-07 | Villarreal | | 0-2 |  | Napoli | GS | ||
L | 2011-11-22 | Bayern München | | 3-1 | | Villarreal | GS | ||
L | 2011-11-02 | Villarreal | | 0-3 |  | Manchester City | GS | ||
L | 2011-10-18 | Manchester City | | 2-1 | | Villarreal | GS | ||
L | 2011-09-27 | Napoli | | 2-0 | | Villarreal | GS | ||
L | 2011-09-14 | Villarreal | | 0-2 | | Bayern München | GS | ||
L | 2009-04-15 | Arsenal |  | 3-0 | | Villarreal | QF | ||
D | 2009-04-07 | Villarreal | | 1-1 | | Arsenal | QF |
